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ADR in the warehouse: hazard classes, separation and exempt quantities

How to correctly classify, label, and segregate hazardous goods

On a warehouse that receives or dispatches dangerous goods, ADR regulations are part of daily work. ADR — the European convention for road transport of dangerous goods — determines how goods are classified, labeled, separated, and documented. You don't need to know every single rule by heart, but you should be able to recognize dangerous goods, understand the labeling, and know when to ask.

§The nine hazard classes in ADR

Farligt gods inddeles efter den dominerende fare i ni klasser. Klassen styrer både faresedlen på kolliet og hvilke stoffer, der ikke må stå eller sendes sammen:

ClassType of hazardExample of everyday item.
1Explosive substancesCertain pyrotechnic and explosive products
2GasesPressure cylinders, gas cans, certain spray cans
3Flammable liquidsPaint, thinner, spirits, certain cleaning agents
4Flammable/self-igniting solidsCertain metal powders ignition sources
5Oxidising substances and peroxidesBleach, certain fertilizers
6Toxicity by inhalationCertain pesticides test material
7Radioactive substancesMeasuring and medical sources
8Corrosive substancesAcids, bases, drain cleaner, battery acid
9Various hazardous substancesLithium batteries, hazardous substances

§UN number and hazard labels

Each substance has a four-digit UN number, an official proper shipping name and possibly a packing group indicating the hazard level. Packages are marked with diamond-shaped hazard labels that show the class with colour and symbol — e.g. a flame for flammable, a skull for toxic, a beaker symbol for corrosive. Learn the symbols so you can immediately see what you are dealing with.

§Separation and co-loading

Some classes must not stand or be transported together because they can react dangerously with each other. An oxidizing substance leaking onto flammable material can for example greatly promote a fire. ADR and company rules contain compatibility tables that tell what can and cannot stand together. Follow them consistently – also when busy and the temptation to 'just put it here' is great.

§Limited quantities and exemptions

ADR has more lenient rules below certain quantity thresholds. If only small quantities are sent per package and per transport unit — the so-called exempt quantity/value table — a number of the heavy requirements fall away. The thresholds depend on the substance's class and package group and are set out in the ADR. This is not something you estimate by feel: if you are in doubt about whether a shipment is below the threshold, ask a responsible person or the company's safety adviser.

§Your role and training

The one who handles or prepares dangerous goods must have training appropriate to the task. Companies with a certain amount of dangerous goods must appoint a safety adviser with a special exam. As a warehouse worker you must know the marking follow the separation rules use the prescribed protective equipment and only do what you have been trained to do.

When you know the nine hazard classes can read hazard labels and UN numbers keep incompatible substances separate and know when to ask about exemption amounts and training you handle hazardous goods safely and legally in the warehouse.